Ammonium bifluoride is not known to
bioaccumulate or persist in the environment more than a few days. However it
will decompose in moist environments liberating hydrofluoric acid and ammonia.
Ammonium bifluoride is corrosive and can
corr ode most metals. It is not flammable or explosive. Ammonium bifluoride
will react with water (inc luding perspiration) to form hydrofluoric acid.
Exposure of ammonium bifluoride to strong
acids, strong bases, water or high temperatures can cause decomposition.
Decomposition of ammonium bifluoride will result in the liberation of hydrogen
fluoride, ammonia and nitrogen oxide gases.
The concentrations of ammonium bifluoride
typically found in consumer products may pose risk of symptoms due to skin,
ingestion or inhalation exposure. Persons suffering from eye or ingestion
exposure to consumer strengt h ammonium bifluoride products may experience
symptoms similar to persons exposed to industrial strength ammonium bifluoride .
Exposures to industrial strength ammonium
bifluoride can produce the following adverse health affects:
1. Contact
Skin exposures can cause symptoms ranging from minor skin irritation to painful
redness and swelling. Severe burns can
occur if treatment is delayed after exposure to ammonium bifluoride. Eye expos
ure to ammonium bifluoride may result in severe eye irritation, burns or even
blindness.
2. Inhalation
The inhalation of ammonium bifluoride
can cause symptoms ranging from nose and throat irritation to coughing and
difficulty breathing. Aspiration may cause pulmonary edema and pneum onitis
(fluid on the lungs and inflammation of the lungs). Repeated or prolonged
exposur es may cause sore throat, nosebleeds and chronic bronchitis. Prolonged
exposure may cause hypocalcemia with nervous
problems (tetany) and cardiac arrhythmia (reduced calcium levels, spasms
and irregular heart beat).
3. Ingestion
The ingestion of ammonium bifluoride may
cause burns of the mouth and throat and
perforation of the esophagus and stomach. N ausea, bloody vomiting, abdominal
pain, diarrhea, difficulty breathing, swelling of the throat, loss of
consciousness, coma and heart failure can also occur. The ingestion of ammonium bifluoride may be
fatal.
4. Other Effects
The International Agency for Research on
Cancer (IARC) has not determined ammonium bifluoride to be carcinogenic (cancer
causing). During most exposures, ammonium bifluoride will dissoc iate to
release hydrofluoric acid. First aid techniques for treatment to hydrof luoric
acid exposures are unique. They require a rapid response and the use of calcium
(most commonly calcium gluconate
solutions or gels) to scavenge and neutralize the fluoride ion.
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